Yes, the Win2PDF printer supports these editions of Windows 10 using the familiar ‘Print to PDF’ interface as in past editions.
•Windows 10 Home
•Windows 10 Pro
•Windows 10 Enterprise
•Windows 10 Education
Win2PDF does NOT support these mobile editions of Windows 10, however.
•Windows 10 Mobile
•Windows 10 Mobile Enterprise
•Windows 10 S
You can switch from Windows 10 S to Windows 10 Pro easily at any time through the Microsoft Store.
The mobile editions are designed primarily for phones and tablet devices that run on non-Intel processors. These editions only support printers that are built in to Windows, so they don't support Win2PDF.